I don't quite have the setup you do, but I recently bought an optical slave. I'm using the 430EX on camera and putting an older flash on the slave box. To do this, I had to put the 430EX on M so that my slave would trigger at the right time. Unless you are on M, any optical slave will fire too soon, and the light will have no effect on your image.
I don't know for sure if the Canon wireless will work if both flashes or on M, but you might give it a try. It'll add a little bit more work getting your ratios correct. Because of that preflash, unless you have a slave sensor that is designed to recognize it, you won't get your flash timing correct.
Someone made a small slave flash a few years ago that could be set about 4 or 5 different ways to adjust for preflashes. It really wasn't a great product, and barely worked, but the concept was a good one.
- Craig
There are two types of photographers, those that shoot Canon & those that wish they could.
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